Call Us 080-41656200 (Mon-Sat: 10AM-8PM)
Free Shipping above Rs. 1499
Cash On Delivery*

Bicyclo[2.2.1] heptane-carboxamides

 

Marketed By :  LAP LAMBERT Academic Publishing   Sold By :  Kamal Books International  
Delivery in :  10-12 Business Days

 

Check Your Delivery Options

 
Rs. 3,651

Availability: In stock

 
  • Product Description
 

This book summarizes efforts toward the chiral synthesis of norcamphor and analogues. Intermediate amide was resolved and X-ray structure of the enantiomers solved. The absolute configuration of the ketones was inferred from that of corresponding amide precursor. The conversion of the precursors to the ketones was performed and proved to be stereospecific. This was based on the hydrolysis of chloronitriles to ketones via amides. Since chlorine gives anomalous dispersion of X-rays, the chlorinated intermediates could be used to assign absolute configuration of the ketones. The generated synthesized chiral ketones play a critical role in the synthesis of disubstituted cyclopentanes as demonstrated in the synthesis of stereoselective hydroxylation of the bicyclic amides and subsequent ketonization. Lactonization followed by hydrolysis gives a cyclopentane with 3 or 4 well defined stereogenic centers.

Product Specifications
SKU :COC49647
AuthorMartin Thuo Mwangi
LanguageEnglish
BindingPaperback
Number of Pages76
Publishing Year2010-09-14T00:00:00.000
ISBN978-3838328003
Edition1 st
Book TypeOrganic chemistry
Country of ManufactureIndia
Product BrandLAP LAMBERT Academic Publishing
Product Packaging InfoBox
In The Box1 Piece
Product First Available On ClickOnCare.com2015-04-08 00:00:00