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Chemistry of Deoxidization Processes in Molten Ionic Halides

 

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  • Product Description
 

Physico-chemical peculiarities of interactions of oxide-containing admixtures in molten salts with different kinds of deoxidizing agents (halogen-containing gases, metal cations and getters) are analyzed in connection with the oxoacidic properties of the said melts. An approach giving possibility to extend the usability of existing experimental data to the case of melts possessing distinguished compositions is proposed. The juxtaposition of the obtained parameters of purification can be made using the primary medium effect of oxide ion (the oxobasicity index). Thermodynamic predictions and kinetic regularities of treatment of halide melts by action of gaseous hydrogen halides and halogen derivatives of hydrocarbons are discussed. The action of cations and getters on molten salts is considered on example of molten cesium iodide as initial material for the growth of optical single crystals. The efficiency of both deoxidizing agents increases with the rise of melting point of the formed metal oxide that makes this parameter to be the main criterion of choice of appropriate scavenger. The effect of cations and getters on the quality of the final optical crystals is shown.

Product Specifications
SKU :COC53636
AuthorVictor Cheginets and Tatyana Rebrova
LanguageEnglish
BindingPaperback
Number of Pages196
Publishing Year2014-07-22T00:00:00.000
ISBN9783659578243
Edition1 st
Book TypePhysical chemistry
Country of ManufactureIndia
Product BrandLAP LAMBERT Academic Publishing
Product Packaging InfoBox
In The Box1 Piece
Product First Available On ClickOnCare.com2015-06-08 00:00:00
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