Category

share

Development of PCP Pincer Complexes

Development of PCP Pincer Complexes

 

Marketed By :  VDM Verlag Dr. Müller   Sold By :  Kamal Books International  
Delivery in :  10-12 Business Days

 
₹ 3,651

Availability: Out of stock

 

Delivery :

5% Cashback on all Orders paid using MobiKwik Wallet T&C

Free Krispy Kreme Voucher on all Orders paid using UltraCash Wallet T&C
Product Out of Stock Subscription

(Notify me when this product is back in stock)

  • Product Description
 

Novel pincer complexes have been explored as catalysts in the activation of unreactive C-H and C-Cl bonds. In the dehydrogenation of alkanes, two PCP pincer iridum complexes have demonstrated similar kinetic aspects. This observation indicates both complexes undergo a dissociative pathway to form the same 14-electron Ir(I) intermediate (PCP)Ir through which the dehydrogenation of alkanes occurs. In the hydroxylation 1-propanol to 1,3-diol, two pincer-ligated platinum complexes present much higher activity and selectivity than the original Shilov catalyst, tetrachloroplatinate. Moreover, both complexes are able to catalyze this transformation even upon replacement of hexachloroplatinate by more economical copper(II) chloride as an oxidant. In the study of activation of arene chlorine bond, an effective one-pot catalytic system has been developed to apply PCP pincer palladium complex as an active catalyst to mediate the cross-coupling reaction between phenylacetylene and a wide array of electronically deactivated, non-activated and activated as well as hindered aryl chlorides with modest to excellent yields in the presence of zinc chloride.

Product Specifications
SKU :COC39505
Country of ManufactureIndia
Product BrandVDM Verlag Dr. Müller
Product Packaging InfoBox
In The Box1 Piece
Product First Available On ClickOnCare.com2015-01-08
0 Review(s)