Kinetic features of the base hydrolysis of schiff base complexes

Kinetic features of the base hydrolysis of schiff base complexes


Marketed By :  LAP LAMBERT Academic Publishing   Sold By :  Kamal Books International  
Delivery in :  10-12 Business Days

₹ 5,066

Availability: Out of stock


Delivery :

5% Cashback on all Orders paid using MobiKwik Wallet T&C

Free Krispy Kreme Voucher on all Orders paid using UltraCash Wallet T&C
Product Out of Stock Subscription

(Notify me when this product is back in stock)

  • Product Description

This work deals with the preparation, characterization and kinetic studies on base hydrolysis of some Fe(II) Schiff base amino acid complexes.The prepared complexes were found to be of 1:2 or 1:1 stoichiometry and non – electrolytic character, solubility measurements of these complexes showed them as hydrophobic in nature. The base hydrolysis reaction of the prepared complexes was carried out in aqueous, co-organic media and in the presence of added salts. The kinetic measurements confirmed the pseudo 1st – order rate dependence in [complex] and 2nd – order in [OH-]. A relevant mechanism was suggested in which the parallel attack of OH- ion on the central Fe(II) atom and the dissociation of the first ligand is provided as rate – determining step. The observed decrease of base hydrolysis rate constant kobs. with increasing the mole fraction of co-organic solvent indicates solute – solvent interaction between delocalized charge in complex and dispersion centers on solvent molecules.

Product Specifications
SKU :COC40636
Country of ManufactureIndia
Product BrandLAP LAMBERT Academic Publishing
Product Packaging InfoBox
In The Box1 Piece
Product First Available On ClickOnCare.com2015-02-08
0 Review(s)