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Metallofullerenes

 

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  • Product Description
 

The characterisation of the most novel metallofullerenes up to 2004 has been theoretically and systematically discussed in this Ph-D thesis presented in 2005 at Universitat Rovira i Virgili and reissued in 2011. From the structural point of view, metallofullerenes can be divided into three main groups according to the metal position: endohedral, heterohedral and exohedral metallofullerenes. The main families of compounds studied are [email protected] (n = 0-3, M = Y, La; k = 68, 78, 80) for endohedrals, CxMn (x = 56, 57, 58, 59; M = Pt, Ir, Os; n = 1, 2) for heterohedrals and Ck-{M(PH3)2}n (k = 60, 70, 84; M = Pt, Pd, Ni; n = 1, 2, 4, 6) for exohedrals. The present research is a step forward in the knowledge of each of these families of compounds, and in particular, in our understanding of the metal-carbon bond, isomerism and reactivity. The DFT method proved to be an excellent computational tool for providing good geometries, for solving the intricacies of the different metal-carbon bonds, for reproducing experimental data (ionization potentials and electron affinities) and also for making predictions about isomerism stability and reactivity.

Product Specifications
SKU :COC98243
AuthorJosep Maria Campanera Alsina
LanguageEnglish
BindingPaperback
Number of Pages236
Publishing Year2011-10-20T00:00:00.000
ISBN978-3846520376
Edition1 st
Book TypeChemistry
Country of ManufactureIndia
Product BrandLAP LAMBERT Academic Publishing
Product Packaging InfoBox
In The Box1 Piece
Product First Available On ClickOnCare.com2015-08-18 00:00:00