From the begging of the nanotechnology era, it was essential part to create new nano efficient material that should be used as multifunctional devices. The problem keeping in my mind, an advanced material organic-inorganic nano-composite electrically semiconducting cation-exchanger for preparation, phisico-chemical characterization and their tremendous applications has been discussed as compilation work in the form of a book. We discussed some electrically conducting ortho derivatives of aniline as, tolidine, anisidine with inorganic cation exchanger having some metals with phosphate group viz. thorium (Th), tin (Sn). The main objective of our proposed work is to explain advance class organic-inorganic hybrid materials and how to apply these materials in analytical and electro analytical applications.