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Oxidation of Schiff Base Complexes - Kinetic Aspects


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  • Product Description

In this work, the reaction between Fe(II) Schiff base complexes and H2O2 was carried out in aqueous, co-organic media and in the presence of added salts. Moreover the activation parameters were calculated and discussed. The Kinetic measurements confirmed the pseudo 1st – order rate dependence in both [complex] and [H2O2]. The suggested mechanism was involved the attack of hydroperoxo ion (HOO-) on the electrophilic carbon azomethine to form the intraperoxo – complex intermediate via which the oxidation reaction of Fe(II) to Fe(III) is catalyzed in slow steps. There is an enhancement of the rate constant upon adding salts with low concentrations, which agrees with the anionic nature of the reactants in the rate controlling step, RCS.

Product Specifications
SKU :COC40604
AuthorLobna Abdel-Mohsen Ebaid Nassr
Number of Pages228
Publishing Year3/27/2012
Edition1 st
Book TypePhysical chemistry
Country of ManufactureIndia
Product BrandLAP LAMBERT Academic Publishing
Product Packaging InfoBox
In The Box1 Piece
Product First Available On ClickOnCare.com2015-02-08 00:00:00