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Trimetallic Nitride Template Endohedral Fullerene Derivatives

 

Marketed By :  Scholars' Press   Sold By :  Kamal Books International  
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  • Product Description
 

Among renewable energy sources, solar energy has the potential to meet the world's growing demand for energy in the future. Currently there are many research efforts to prepare materials for photovoltaics including organic molecules. Among them, fullerene derivatives have been identified as promising materials for the construction of plastic solar cells. In this work the preparation and electrochemical properties of donor–acceptor systems based on trimetallic nitride endohedral metallofullerenes (TNT-EMFs) for solar energy conversion is described. It was found that TNT-EMFs have an enhanced ability to stabilize charge separated states formed upon light irradiation when compared to empty cage fullerene analogues. Optimal conditions for preparing cyclopropanated Bingel-Hirsch derivaties of the most common TNT-EMFs were found. Novel D-A systems were prepared using this strategy and their electrochemical properties revealed that they form films by electro-oxidative polymerization. These films generate electrical current upon light irradiation. This work is a guideline for anyone interested in exploring the chemistry and electrochemical properties of these novel materials.

Product Specifications
SKU :COC77798
AuthorJulio R. Pinzón
LanguageEnglish
BindingPaperback
Number of Pages212
Publishing Year2014-08-08T00:00:00.000
ISBN9783639719826
Edition1 st
Book TypeOrganic chemistry
Country of ManufactureIndia
Product BrandScholars' Press
Product Packaging InfoBox
In The Box1 Piece
Product First Available On ClickOnCare.com2015-10-08 00:00:00